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41.
The 1667-MHz ground-state hydroxyl (OH) line has been observed towards positions on Puppis A as well as in the immediate vicinity of this supernova remnant (SNR). The spectra at two positions on Puppis A show absorption lines at velocities less than +7.6 km s1, and emission lines above this velocity. Analysis of all four 18 cm OH lines indicates that Puppis A must lie between the OH clouds seen in absorption and emission, giving it a v lsr of +7.6 km s1. This implies that the kinematic distance to Puppis A is The OH clouds in front of Puppis A are slightly anomalously excited, as shown by analysis of the four 18 cm OH lines at the two observed positions on Puppis A. There is no evidence of any interaction of the SNR with the clouds in front of and behind it.  相似文献   
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In the Northern Andes of Ecuador, a broad Quaternary volcanic arc with significant across-arc geochemical changes sits upon continental crust consisting of accreted oceanic and continental terranes. Quaternary volcanic centers occur, from west to east, along the Western Cordillera (frontal arc), in the Inter-Andean Depression and along the Eastern Cordillera (main arc), and in the Sub-Andean Zone (back-arc). The adakite-like signatures of the frontal and main arc volcanoes have been interpreted either as the result of slab melting plus subsequent slab melt–mantle interactions or of lower crustal melting, fractional crystallization, and assimilation processes. In this paper, we present petrographic, geochemical, and isotopic (Sr, Nd, Pb) data on dominantly andesitic to dacitic volcanic rocks as well as crustal xenolith and cumulate samples from five volcanic centers (Pululagua, Pichincha, Ilalo, Chacana, Sumaco) forming a NW–SE transect at about 0° latitude and encompassing the frontal (Pululagua, Pichincha), main (Ilalo, Chacana), and back-arc (Sumaco) chains. All rocks display typical subduction-related geochemical signatures, such as Nb and Ta negative anomalies and LILE enrichment. They show a relative depletion of fluid-mobile elements and a general increase in incompatible elements from the front to the back-arc suggesting derivation from progressively lower degrees of partial melting of the mantle wedge induced by decreasing amounts of fluids released from the slab. We observe widespread petrographic evidence of interaction of primary melts with mafic xenoliths as well as with clinopyroxene- and/or amphibole-bearing cumulates and of magma mixing at all frontal and main arc volcanic centers. Within each volcanic center, rocks display correlations between evolution indices and radiogenic isotopes, although absolute variations of radiogenic isotopes are small and their values are overall rather primitive (e.g., εNd = +1.5 to +6, 87Sr/86Sr = 0.7040–0.70435). Rare earth element patterns are characterized by variably fractionated light to heavy REE (La/YbN = 5.7–34) and by the absence of Eu negative anomalies suggesting evolution of these rocks with limited plagioclase fractionation. We interpret the petrographic, geochemical, and isotopic data as indicating open-system evolution at all volcanic centers characterized by fractional crystallization and magma mixing processes at different lower- to mid-crustal levels as well as by assimilation of mafic lower crust and/or its partial melts. Thus, we propose that the adakite-like signatures of Ecuadorian rocks (e.g., high Sr/Y and La/Yb values) are primarily the result of lower- to mid-crustal processing of mantle-derived melts, rather than of slab melts and slab melt–mantle interactions. The isotopic signatures of the least evolved adakite-like rocks of the active and recent volcanoes are the same as those of Tertiary ”normal” calc-alkaline magmatic rocks of Ecuador suggesting that the source of the magma did not change through time. What changed was the depth of magmatic evolution, probably as a consequence of increased compression induced by the stronger coupling between the subducting and overriding plates associated with subduction of the aseismic Carnegie Ridge.  相似文献   
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We present new reference values for nineteen USGS, GSJ and GIT‐IWG rock reference materials that belong to the most accessed samples of the GeoReM database. The determination of the reference values and their uncertainties at the 95% confidence level follows as closely as possible ISO guidelines and the Certification Protocol of the International Association of Geoanalysts. We used analytical data obtained by the state‐of‐the‐art techniques published mainly in the last 20 years and available in GeoReM. The data are grouped into four categories of different levels of metrological confidence, starting with isotope dilution mass spectrometry as a primary method. Data quality was checked by careful investigation of analytical procedures and by the application of the Horwitz function. As a result, we assign a new and more reliable set of reference values and respective uncertainties for major, minor and a large group of trace elements of the nineteen investigated rock reference materials.  相似文献   
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In a previous paper, we have shown that long-term cloud and solar observations (1965–2013) in Bergen, Norway (60.39°N, 5.33°E) are compatible with a largely cloud dominated radiative climate. Here, we explicitly address the relationship between the large scale circulation over Europe and local conditions in Bergen, identifying specific circulation shifts that have contributed to the observed cloud and solar variations. As a measure of synoptic weather patterns, we use the Grosswetterlagen (GWL), a daily classification of European weather for 1881–2013. Empirical models of cloud cover, cloud base, relative sunshine duration, and normalised global irradiance are constructed based on the GWL frequencies, extending the observational time series by more than 70 years. The GWL models successfully reproduce the observed increase in cloud cover and decrease in solar irradiance during the 1970s and 1980s. This cloud-induced dimming is traced to an increasing frequency of cyclonic and decreasing frequency of anticyclonic weather patterns over northern Europe. The changing circulation patterns in winter can be understood as a shift from the negative to the positive phase of the North Atlantic and Arctic Oscillation. A recent period of increasing solar irradiance is observed but not reproduce by the GWL models, suggesting this brightening is associated with factors other than large scale atmospheric circulation, possibly decreasing aerosol loads and local cloud shifts.  相似文献   
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The relationship between surface bubble composition and gas flux to the atmosphere was examined at five large seeps from the Coal Oil Point seep field (Santa Barbara Channel, CA, USA). The field research was conducted using a flux buoy designed to simultaneously measure the surface bubbling gas flux and the buoy’s position with differential GPS, and to collect gas samples. Results show that the flux from the five seeps surveyed a total of 11 times ranged from 800–5,500 m3 day?1. The spatial distribution of flux from the five seeps was well described by two lognormal distributions fitted to two flux ranges. The seafloor and sea surface composition of bubbles differed, with the seafloor bubbles containing significantly more CO2 (3–25%) and less air (N2 and O2). At the sea surface, the mole fraction of N2 correlated directly with O2 (R 2 = 0.95) and inversely with CH4 (R 2 = 0.97); the CO2 content was reduced to the detection limit (<0.1%). These data demonstrate that the bubble composition is modified by gas exchange during ascent: dissolved air enters, and CO2 and hydrocarbon gases leave the bubbles. The mean surface composition at the five seeps varied with water depth and gas flux, with more CH4 and higher CH4/N2 ratios found in shallower seeps with higher flux. It is suggested that the CH4/N2 ratio is a good proxy for total or integrated gas loss from the rising bubbles, although additional study is needed before this ratio can be used quantitatively.  相似文献   
47.
57Fe Mössbauer spectra of natural glasses (pumices and obsidians) and of synthetic glasses of granitic composition have been analyzed. — Ferric iron is found in tetrahedral coordination if enough M+-cations are available to balance the charge of both M+Fe3+O2 and M+AlO2 complexes. In other compositions the ratio of tetrahedrally to octahedrally coordinated Fe3+ depends on the ratio of mono-to divalent cations. — Ferrous iron occurs in two distinctly different octahedral sites. The existence of these sites can be attributed to different anionic units adjacent to Fe2+. The degree of polymerization of these units is reflected in the quadrupole splitting. The anionic units adjacent to Fe2+ are depolymerized for increasing mean Z/r 2 of the network modifiers, which do not stabilize M3+ in the tetrahedra by local charge balance. — Increasing pressure diminishes the geometric differences between these types of ferrous iron-oxygen-octahedra, which gives rise to a more even distribution of Fe2+ among these sites and thereby to an ordering in the network of melts.  相似文献   
48.
A study of lunar impact crater size-distributions   总被引:3,自引:0,他引:3  
Discrepancies in published crater frequency data prompted this study of lunar crater distributions. Effects modifying production size distributions of impact craters such as surface lava flows, blanketing by ejecta, superposition, infilling, and abrasion of craters, mass wasting, and the contribution of secondary and volcanic craters are discussed. The resulting criteria have been applied in the determination of the size distributions of unmodified impact crater populations in selected lunar regions of different ages. The measured cumulative crater frequencies are used to obtain a general calibration size distribution curve by a normalization procedure. It is found that the lunar impact crater size distribution is largely constant in the size range 0.3 km ?D ? 20 km for regions with formation ages between ≈ 3 × 109 yr and ? 4 × 109 yr. A polynomial of 4th degree, valid in the size range 0.8 km ?D ? 20 km, and a polynomial of 7th degree, valid in the size range 0.3 km ?D ? ? 20 km, have been approximated to the logarithm of the cumulative crater frequencyN as a function of the logarithm of crater diameterD. The resulting relationship can be expressed asND α(D) where α is a function depending onD. This relationship allows the comparison of crater frequencies in different size ranges. Exponential relationships with constant α, commonly used in the literature, are shown to inadequately approximate the lunar impact crater size distribution. Deviations of measured size distributions from the calibration distribution are strongly suggestive of the existence of processes having modified the primary impact crater population.  相似文献   
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